tags
peroxidehydrogensulfatesulfuric acidbarium saltscalciumsulfur

video tutorial Sulfuric acid from sulfur using hydrogen peroxide

Summary: The clip shows an improvised setup to make sulfuric acid by burning sulfur and absorbing the resulting sulfur dioxide in a hydrogen peroxide solution. A funnel and tin foil apparatus directs gas into a flask connected to a vacuum pump. About 10 g of sulfur is burned; the sulfur dioxide is drawn into the peroxide, turning the solution acidic. The mixture heats as the reaction proceeds, and some SO2 eventually escapes the absorption. After cooling, the solution is tested and found to be very acidic (pH < 1), indicating sulfuric acid formation. Since soluble barium salts aren’t available, calcium chloride is added to precipitate calcium sulfate. The solid is filtered, dried in an oven, yielding 13.7 g of calcium sulfate, likely with some water of hydration (hemihydrate). Through calculation, the starting hydrogen peroxide solution is estimated to be at least 4.3% H2O2 by weight, with uncertainty. The video hints at possible future use of residual peroxide and thanks viewers.

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