tags
Nitrogen dioxidenitrogensodium carbonatebenzylnitricnitrogen trioxidebenzaldehydediDinitrogen trioxide
video tutorial Preparation of liquid nitrogen dioxide
- Celebrates reaching 1000 subscribers and uses old coins to explore nitrogen oxides via nitric acid.
- Describes setting up equipment with drying and cooling to condense nitrogen dioxide species into a blue liquid.
- Observes brown nitrogen dioxide gas initially, followed by a blue liquid consistent with a nitrogen dioxide/nitrogen trioxide equilibrium (and traces of dinitrogen tetroxide).
- Notes the reaction is exothermic and that apparatus is purged and quenched after the run; product appears to be a blue liquid that contains nitrogen oxides.
- Performs small-scale follow-up tests on the product with water, hypoxylamine hydrochloride, ethanol, benzyl alcohol, and potassium hydroxide, reporting various reactions and strong odors; remarks the method is not particularly practical.
- Concludes with reflections on the NO2/N2O4 equilibrium and possible involvement of nitric oxide, and invites viewer ideas.
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