tags
Nitrogen dioxidenitrogensodium carbonatebenzylnitricnitrogen trioxidebenzaldehydediDinitrogen trioxide

video tutorial Preparation of liquid nitrogen dioxide

  • Celebrates reaching 1000 subscribers and uses old coins to explore nitrogen oxides via nitric acid.
  • Describes setting up equipment with drying and cooling to condense nitrogen dioxide species into a blue liquid.
  • Observes brown nitrogen dioxide gas initially, followed by a blue liquid consistent with a nitrogen dioxide/nitrogen trioxide equilibrium (and traces of dinitrogen tetroxide).
  • Notes the reaction is exothermic and that apparatus is purged and quenched after the run; product appears to be a blue liquid that contains nitrogen oxides.
  • Performs small-scale follow-up tests on the product with water, hypoxylamine hydrochloride, ethanol, benzyl alcohol, and potassium hydroxide, reporting various reactions and strong odors; remarks the method is not particularly practical.
  • Concludes with reflections on the NO2/N2O4 equilibrium and possible involvement of nitric oxide, and invites viewer ideas.

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