tags
OTCsodiumsodium chloridehydrogenhydroxylamine hydrochloridesodium bisulfiteCopper hydroxidecopperhydroxylamine
video tutorial Copper (I) oxide and 'Filter Paper Art'
- Two routes to prepare copper oxide from copper sulfate are demonstrated, highlighting the interplay of science and art.
- Plan A: Reduce copper sulfate with hydroxylamine hydrochloride in a basic solution to copper oxide, but results are a fine, air-oxidizing precipitate that turns black; yield and handling issues prompt an alternative method.
- Plan B: A faster method using copper sulfate, sodium bisulfite, sodium chloride, and sodium hydroxide in hot water yields a stable orange copper oxide with better yield (~67%), obtained as a dry orange powder after filtration and ethanol washing.
- Additional observations: treating the product with nitric acid oxidizes it to copper nitrate (blue), and hydrogen peroxide in the presence of copper oxide decomposes to oxygen while oxidizing some oxide to a darker color; a demonstration coats paper with oxide.
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