tags
benzoinbenzyl alcoholalcoholbenzaldehydehypochloritecyanidecyanidesethanol
video tutorial Benzoin condensation the 'old school' way using a cyanide catalyst
- Topic: classic benzoin condensation using cyanide as a catalyst (old-school method).
- Safety and disposal: cyanide is highly toxic; dispose of cyanide-containing waste with hypochlorite bleach to form less toxic cyanate.
- Procedure: prepare an aqueous cyanide solution, combine with benzaldehyde dissolved in ethanol, and reflux gently for about two hours; reaction color darkens to orange.
- Workup: allow solvent to evaporate, crystallization forms, cool and crystallize; filter the solid and wash with cold water, then with ice-cold ethanol; dry to a fine powder.
- Product and yield: benzoin obtained (7.2 g) from 10 g benzaldehyde, about 72% yield; recrystallization optional but the product appears pure with a delicate aroma and no almond-like odor.
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